Li, Junjun; Guo, Cong; Bai, Yu; Liu, Wenzhu; Chen, Yang; He, Jialong; Li, Dongdong; Yang, Xinbo; Qiu, Qingqing; Chen, Tao; Yu, Junsheng; Huang, Yuelong; Yu, Jian

ADVANCED SCIENCE

2022, 9,

Li, Junjun; Guo, Cong; Bai, Yu; Liu, Wenzhu; Chen, Yang; He, Jialong; Li, Dongdong; Yang, Xinbo; Qiu, Qingqing; Chen, Tao; Yu, Junsheng; Huang, Yuelong; Yu, Jian

The development of high-performance dopant-free silicon solar cells is severely bottlenecked by opaque electron selective contact. In this paper, high transmittance (80.5% on glass) and low work function (2.92 eV) lithium fluoride (LiFx)/MgFxOy electron contact stack by tailoring the composition of MgFxOy hybrid film is reported. This hybrid structure exhibits a high conductivity (2978.4 S cm(-1)) and a low contact resistivity (2.0 m omega cm(2)). The element profile of LiFx/MgFxOy contact is measured and the reaction kinetics is analyzed. As a proof-of-concept, this electron selective contact is applied for dopant-free silicon solar cells. An impressive efficiency of 21.3% is achieved on dopant-free monofacial solar cell with molybdenum oxide (MoOx)/zinc-doped indium oxide (IZO) hole contact. An efficiency bifaciality of 71% is obtained for dopant-free bifacial solar cell with full-area LiFx/MgFxOy/ITO (tin-doped indium oxide) transparent electron contact. It is the highest efficiency bifaciality so far for dopant-free bifacial solar cells to the best knowledge. Both cell configurations with LiFx/MgFxOy contacts show excellent environment stability. The cell efficiency maintains more than 95% of its initial value after keeping in air for 1500 h. This work provides a new idea to achieve transparent electron contact, showing a great potential for high-efficiency and low-cost optoelectronic devices.