摘要
To gain deep insight into the Morphological effect of NixMg1 (-) O-x catalysts on the reaction of CO2 reforming with methane, we designed and fabricated three different spatial structural NixMg1 (-) O-x catalysts. These NixMg1 (-) O-x catalysts with specific models such as rod, sheet and sphere, exhibited various activity and stability in CO2 reforming reaction. Herein NixMg1 (-) O-x nanorods displayed higher catalytic activity, in which methane conversion was up to 72% and CO2 conversion was 64% at 670 degrees C with a space velocity of 79,200 mL/(g(cat) h), compared with nanosheet and nanosphere counterparts. Furthermore, both catalysts of NixMg1 (-) O-x nanorod and nanosheet showed a high resistance toward coke deposition and sintering of active sites in the process of CO2 reforming of methane. (C) 2017 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights reserved.