Principles and Applications of Enantioselective Hydroformylation of Terminal Disubstituted Alkenes
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作者
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刊物名称
ACS Catal.
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年、卷、文献号
2015, 5,
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关键词
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摘要
Asymmetric hydroformylation has been primarily focused on monosubstituted and 1,2-disubstituted alkenes. In this Perspective, progress in enantioselective hydroformylation of terminal disubstituted alkenes is outlined on the basis of different categories of substrates. The origins of the commonly observed low degree of enantioselectivity are discussed. Examples with unconventional regioselectivity are also rationalized.