Silver-mediated self-assembly of metallosupramolecular networks based on pyrimidine-containing oxacalix[n]aromatics
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作者
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刊物名称
Crystengcomm
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年、卷、文献号
2011, 13,
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关键词
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摘要
Under self-assembly conditions, the interaction between pyrimidinyl-containing oxacalixaromatics (1 and 2) and silver cation resulted in the formation of two-dimensional coordination networks 3 and 4; single crystal X-ray analysis revealed that complex 3 featured a coordination polymeric structure with ligand 1 arranged in an offset manner along the polymeric chain, while network 4 featured a structure with regular microcyclic channels.