中国科学院上海高等研究院研究生教育

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zhangj@sari.ac.cn
上海市浦东新区海科路100号9A楼323室
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张军，研究员、博士生导师，高潞空气化工产品(上海)能源科技有限公司技术负责人，总工程师。带领团队聚焦国家碳中和战略和能源绿色低碳转型升级的重大需求，以CH4/CO2/H2O等分子的清洁资源化利用为方向，进行光/热/电/催化转化制备高值化学品的应用基础研究，深刻理解在光/热/电/磁等多物理场下的C-H键与C-O键的活化与耦合机制。作为负责人承担国家重大研发计划（2项），自然科学基金、中国科学院战略先导专项（A）、壳牌前瞻科学项目、美国AP/德国BASF等合作研发项目等十余项研究工作，总研发经费超过9000万元。作为通讯作者在ACS Catal.，Applied Cata. B，AIChE, CEJ等期刊发表SCI论文近50余篇，已申请中国发明专利40余项并获授权20项，其中5项专利完成技术转移转化，价值1.91亿元人民币。迄今指导硕博生二十余名，部分进入名企和学校工作，部分留职于本团队升任副研究员或继续攻读在职博士。

在工业化实践方面，作为技术负责人完成全球首套10000Nm3/h级别CH4-CO2重整示范，中国石化联合会的72h现场技术标定认定该技术达到国际领先水平，获得了第十七届中国国际工业博览会银奖，上海电视台、中国科学报、美国Chemical Week, C&EN等几十家主流媒体进行了报道。在此基础上成立高潞有限公司，注册资金4.14亿元，致力于技术商业化推广，目前已签订商业项目2项，项目投资超6亿元。

1、C1化学与工程、光/热/电/磁催化材料系统设计与机理研究

2、CH4/CO2/H2O以及低碳烃醇等分子的资源化利用，氢能源开发

1、第十七届中国国际工业博览会银奖

2、干重整技术获得上海市第一批绿色技术认证

3、干重整技术获得中国石化联合会化工园区绿色技术认证

1. 科技部重大专项，热分解耦合催化还原催化剂设计及反应机理， 2023-2027年， 545 万。

2. 科技部重大专项，CH4/CO2重整制合成气的关键纳米催化技术及工业示范， 2016-2020年， 900 万。

3. 基金委面上基金，等离子体辅助氮化铝水解可控构筑镍基核壳结构及甲烷干重整催化行为研究， 2023-2027，50万

4. 企业横向项目，CO2甲烷重整制合成气， 2011-2016，经费1200万。

5. 企业横向项目，甲烷氧化偶联制C2烃联产合成气技术研发，2022-2024，经费400万。

6. 企业横向项目，美国墨西哥湾沿海地区的天然气重整技术开发，2020-2023，经费400万。

7. 企业横向项目，新一代甲烷干重整技术研发， 2018-2024，经费1800万。

8. 企业横向项目，干重整催化剂升级研发和高压验证，2022-2023，经费278万。

9. 企业横向项目，催化剂升级研发，2021-2022，经费300万。

10. 中国科学院先导(A), CO2大规模重整制合成气的关键技术和工业示范，2013-2017，2900万

1.文章：

[1] Investigation of Atom-Level Reaction Kinetics of Carbon-Resistant Bimetallic NiCo-Reforming Catalysts: Combining Microkinetic Modeling and Density Functional Theory. Jiyang Wang, Yu Fu, Wenbo Kong, Shuqing Li, Changkun Yuan, Jieru Bai, Xia Chen, Jun Zhang*, and Yuhan Sun* . ACS Catalysis 12.8 (2022): 4382-4393.

[2] In situ redispersion of rhodium nanocatalyst for CO2 reforming of CH4. Yu Fu, Wenbo Kong, Bingrong Pan, Changkun Yuan, Shuqing Li, He Zhu, JunZhang*. Journal of Environmental Chemical Engineering, 9.4 (2021) 105790.

[3] How CO2 poisons La2O3 in an OCM catalytic reaction: A study by in situ XRD-MS and DFT Cairu Guan, Yong Yang*, Yaoqi Pang , Zebang Liu, Shenggang Li, Evgeny I. Vovk ,Xiaohong Zhou, Jerry Pui Ho Li, Jun Zhang , Na Yu , Liuliu Long, Jie Hao, Alexander P. van Bavel. Journal of Catalysis, 396 (2021) 202-214.

[4] A highly active and stable Pd/MoC catalyst for hydrogen production from methanol decomposition. Fufeng Cai, Yanjiao Guo, Jessica Juweriah Ibrahim, Jun Zhang*, Yuhan Sun. Applied Catalysis B: Environmental, 299 (2021) 120648.

[5] Nickel nanoparticles with interfacial confinement mimic noble metal catalyst in methane dry reforming. Wenbo Kong, Yu Fu, Lei Shi, Shenggang Li, Evgeny Vovk, Xiaohong Zhou, Rui Si, Bingrong Pan, Changkun Yuan, Shuqing Li, Fufeng Cai, He Zhu, JunZhang*, Yong Yang*, Yuhan Sun*. Applied Catalysis B: Environmental, 285 (2021) 119837.

[6] Anti-sintering non-stoichiometric nickel ferrite for highly efficient and thermal-stable thermochemical CO2 splitting. Jincheng Huang, Yu Fu, Yonghui Zhao, Jun Zhang*, Shuqing Li, Shenggang Li, Guijun Li , Zhenpan Chen, Yuhan Sun*. Chemical Engineering Journal, 404 (2021) 127067.

[7] Design of a carbon-resistant Ni@S-2 reforming catalyst controllable Ni nanoparticles sandwiched in a peasecod-like structure. Jiyang Wang, Yu Fu, Wenbo Kong, Feikai Jin, Jieru Bai, Jun Zhang*, Yuhan Sun*. Applied Catalysis B: Environmental, 282 (2021) 119546.

[8] Methanol steam reforming over ZnPt/MoC catalysts: Effffects of hydrogen treatment. Fufeng Cai*, Jessica Juweriah Ibrahim, Yu Fu, Wenbo Kong, Shuqing Li, Jun Zhang*, Yuhan Sun. Industrial & Engineering Chemistry Research, 59.42 (2020): 18756-18770.

[9] Stable trimetallic NiFeCu catalysts with high carbon resistance for dry reforming of methane. Feikai Jin, Yu Fu, Wenbo Kong, Jiyang Wang. Fufeng Cai, Changkun Yuan, Bingrong Pan, Jun Zhang*, Yuhan Sun*. ChemPlusChem, 85.6 (2020) 1120-1128.

[10] Dually Confined Ni Nanoparticles by Room-Temperature Degradation of AlN for Dry Reforming of Methane, Shuqing Li, Yu Fu, Wenbo Kong, Bingrong Pan, Changkun Yuan, Fufeng Cai, He Zhu, Jun Zhang, Yuhan Sun. Applied Catalysis B: Environmental, 277 (2020) 118921.

[11] Low-temperature hydrogen production from methanol steam reforming on Zn-modified Pt/MoC catalysts. Fufeng Cai, Jessica Juweriah Ibrahim, Yu Fu, Wenbo Kong, Jun Zhang*, Yuhan Sun*. Applied Catalysis B, 264 (2020) 118500.

[12] Cobalt-based ferrites as efficient redox materials for thermochemical two-step CO2-splitting: enhanced performance due to cation diffusion. Jincheng Huang, Yu Fu, Shuqing Li, Wenbo Kong, Jun Zhang* and Yuhan Sun*. Sustainable Energy & Fuels, 3.4 (2019) 975-984.

[13] Investigation of the role of Nb on Pd-Zr-Zn catalyst in methanol steam reforming for hydrogen Production. Fufeng Cai , Peijing Lu , Jessica Juweriah Ibrahim, Yu Fu, Jun Zhang*, Yuhan Sun*. International journal of hydrogen energy, 44 (2019) 11717-11733.

[14] Enhanced activity of Mg-Fe-O ferrites for two-step thermochemical CO2 splitting. Jincheng Huang, Yu Fu, Shenggang Li, Wenbo Kong, Jun Zhang* and Yuhan Sun*. Journal of CO2 Utilization, 26 (2018) 544-551.

[15] Hydrogenolysis of glycerol over supported bimetallic Ni/Cu catalysts with and without external hydrogen addition in a fixed-bed flow reactor. Fufeng Caia, Donghui Pan, Jessica Juweriah Ibrahim, Jun Zhang*, Guomin Xiao*. Applied Catalysis A: General, 564 (2018) 172-182.

[16] Selective hydrogenolysis of glycerol over acid-modified Co-Al catalysts in a fixed-bed flow reactor, Fufeng Cai, Xianghai Song, Yuanfeng Wu, Jun Zhang*, Guomin Xiao*, ACS Sustainable Chemistry & Engineering, 6.1 (2018) 110-118.

[17] A Nickel-Based Perovskite Catalyst with a Bimodal Size Distribution of Nickel Particles for Dry Reforming of Methane. Yingjie Chai, Yu. Fu, He Feng, Wenbo Kong, Changkun Yuan, Bingrong Pan, Jun Zhang* , Yuhan Sun*, ChemCatChem, 10.9 (2018) 2078-2086.

[18] Temperature-dependent anti-coking behaviors of highly stable Ni-CaO-ZrO2 nanocomposite catalysts for CO2 reforming of methane. Qingjun Chen, Jun Zhang*, Bingrong Pan, Wenbo Kong, Yuhan Sun*, Chemical Engineering Journal, 320 (2017) 63~73.

[19] Self-regeneration of ferrites incorporated into matched matrices for thermochemical CO2 splitting. Yu Fu, Jincheng Huang, Shenggang Li, Jun Zhang* and Yuhan Sun*. Journal of Materials Chemistry A, 4.14 (2016) 5026-5031.

2. 专利

[1]一种高分散纳米复合物催化剂及其制备方法和应用发明专利CN103143364A

[2]用于制合成气或者制氢的催化剂及其制法和应用发明专利CN104084211A

[3]方镁石/尖晶石复合晶相天然气重整催化剂的制备和应用发明专利CN104190427A

[4]纳米复合物催化剂及其制备方法与应用发明专利CN104258864A

[5]一种甲烷-二氧化碳重整反应催化剂及其制备方法发明专利CN102151570A

[6]一种动态铁酸盐储氧材料及其应用发明专利CN105126852A

[7]一种两步甲烷-二氧化碳重整制备醋酸原料气的方法发明专利CN105502288A

[8]一种高分散高负载镍基高活性低温甲烷重整催化剂及其应用发明专利CN105688916A